Abstract
In the present work, information on the integral molar Gibbs energies of mixing is employed to calculate the viscosities of binary substitutional metallic melts. A correlation has been established between the second derivative of the integral molar Gibbs energy of mixing with respect to composition and the corresponding function for the Gibbs energy of activation for viscosity. The viscosities predicted from available thermodynamic data in the case of a number of binary metallic systems using this correlation show satisfactory agreement with the values reported from experimental measurements. The value of this correlation in predicting the viscosities of complex metallic melts is also examined.
Similar content being viewed by others
References
F.D. Richardson:Physical Chemistry of Melts in Metallurgy, Academic Press, Inc., London, 1974, vol. 1, pp. 1–27.
M. Kucharski:Z. Metallkd., 1986, vol. 77, pp. 393–96.
E.A. Moelwyn-Hughes:Physical Chemistry, Pergamon Press, Oxford, 1961.
A.F. Crawley:Metall. Trans., 1972, vol. 3, pp. 971–75.
T. Iida and R.I.L. Guthrie:The Physical Properties of Liquid Metals, Claredon Press, Oxford, 1993, pp. 147–98.
T. Iida, M. Ueda, and Z. Monta:Tetsu-to-Hagané, 1976, vol. 62, pp. 1169–78.
Z. Monta, T. Iida, and M. Ueda:Liquid Metals, Inst. Phys. Conf. Ser. No. 30, Institute of Physics, Bristol, 1976, pp. 600–06.
M. Hirai:Iron Steellnst. Jpn. Int., 1993, vol. 33 (2), pp. 251–58.
E.N. daC. Andrade:Phil. Mag., 1934, vol. 17, pp. 497–732.
Du Sichen, J. Bygdén, and S. Seetharaman:Metall. Mater. Trans. B, 1994, vol. 25B, pp. 519–25.
S. Glasstone, K.J. Laidler, and H. Eyring:The Theory of Rate Process, McGraw-Hill Book Co., New York, NY, 1941.
L.S. Darken:TMS-AIME, 1967, vol. 239, pp. 80–89.
M. Born and H.S. Green:A General Kinetic Theory of Liquid, Cambridge University Press, London, 1949.
Scientific Group Thermodata Europe: SGTE SOLUTION DATABASE.
R. Hultgren, P.D. Desai, D.T. Hawkins, M. Gleiser, and K.K. Kelley:Selected Values of the Thermodynamic Properties of Binary Alloys, ASM, Metals Park, OH, 1973.
M.G. Frohberg and K. Özbagi:Z. Metallkd., 1981, vol. 72, pp. 630–36.
H. Walsdorfer, I. Alpshofen, and B. Predel:Z. Metallkd., 1988, vol. 79, pp. 503–12.
L.Ya. Kozlov, L.M. Romanov, and N.N. Pctrov:Izv. Vyssh. Uchebn. Zaved. Chern. Metall., 1983, vol. 3, pp. 7–11 (Russian).
E. Gebhardt, M. Becher, and E. Tragner:Z. Metallkd., 1953, vol. 44, pp. 379–82.
H. Nakajima:Trans. Jpn. Inst. Met., 1976, vol. 17, pp. 403–07.
T. Iida: Ph.D. Thesis, Tohthoku University, 1970.
N.E. Bodakin, B.A. Baum, and G.V. Tyagunov:Izv. Vyssh. Uchebn. Zaved., Chern. Metall., 1978, vol. 7, pp. 9–13.
T. Iida, Z. Monta, and S. Takeuchi:J. Jpn. Inst. Met., 1975, vol. 39, pp. 1169–75.
E. Gebhardt and G. Wörwag:Z. Metallkd., 1952, vol. 43, pp. 106–08.
B. Djemili, L. Martin-Garin, R. Martin-Garin, and P. Desré:J. Less-Common Met., 1981, vol. 79, pp. 29–37.
K. Kawai and Y. Shiraishi:Handbook of Physico-Chemical Properties at High Temperatures, Iron and Steel Institute of Japan, Tokyo, 1988.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Seetharaman, S., Sichen, D. Estimation of the viscosities of binary metallic melts using Gibbs energies of mixing. Metall Mater Trans B 25, 589–595 (1994). https://doi.org/10.1007/BF02650079
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02650079