Abstract
The Y-Cu binary system was experimentally investigated by DTA and XRD. The DTA results provide evidence for the possible existence of a high-temperature phase transformation in the YCu2 compound. The XRD results confirm a range of solubility for the YCu6 phase. A thermodynamic description for all the phases was obtained by taking into account all experimental data in the literature. A new phase diagram is proposed.
Similar content being viewed by others
Cited References
O. Redlich and A. Kister,Ind. Eng. Chem.,40, 345–348 (1948).
A.H. Daane and F.H. Spedding, U.S. Atomic Energy Commission, 1SC-976,20–21 (1957).
J.H. Wernick and S. Geller,Acta Crystallogr.,12, 662–665 (1959).
A.E. Dwight,Metall. Trans. ASM, 53,479–500 (1961).
R.F. Domagala, J.J. Rausch, and D.W. Levinson,Metall. Trans. ASM,53,137–155(1961).
J. Haefling and A.H. Daane, unpublished data; quoted by C.E. Lundin,The Rare Earths, F.H. Spedding and A.H. Daane, Ed., John Wiley & Sons, Inc., NY, 252–254 (1961).
P.K. Kejriwal and E. Ryba,Acta Crystallogr.,16, 853 (1963).
A.R. Storm and K.E. Benson,Acta Crystollogr.,16,701 (1963).
K. Schubert,Kristallstrukturen zweikomponentiger Phasen, Springer-Verlag, Berlin, 165 (1964) in German.
B. J. Beaudry, unpublished results; quoted by [81Cha].
M. Hillert and L.-I. Staffansson,Acta Chem. Scand.,24, 3618- 3626(1970).
K.H.J. Buschow and A.S. Van Der Goot,Acto Crystallogr. B, 27, 1085–1088(1971).
V.N. Fedorov, A.A. Zhurba,Russ. Metall., No. 1, 137–140 (1975).
D.J. Chakrabarti and D.E. Laughlin,Bull. Alloy Phase Diagrams, 2(3),315–319(1981).
Y.C. Chuang, C.H. Wu, and Y.C. Chang,J. Less-Common Met.,84,201–213(1982).
S. Watanabe and O.J. Kleppa,Metall. Trans. B, 15, 357–368 (1984).
T.D. Djuraev and R. A. Altynaev,Dokl. Akad. Nauk Tadzh. SSR, 29,472(1986).
G. Qi, K. Itagaki, and A. Yazawa,Mater. Trans. JIM, 30,273–282 (1989).
Q. Yang, G. Liu, and Z. Liu,Acta Metall. Sin., 25, 250–254 (1989).
K. Itagaki, G. Qi, S. an Mey, and P.J. Spencer,Calphad, 14,377–384(1990).
A.T. Dinsdale,Calphad, 15(4), 317–432 (1991).
H. Okamoto,J. Phase Equilibria, 13(1), 102–103 (1992).
H.L. Lukas and S.G. Fries,J. Phase Equilibria, 13(5), 532–541 (1992).
R. Konetzki, R. Schmid-Fetzer, A. Watson, B. Argent, S.G. Fries, and H.L. Lukas,Z. Metallkd.,84,569–573 (1993).
T. Tanaka, N. A. Goksen, Z. Morita, and T. Iida,Z. Metallkd.,84, 192–200(1993).
R. Konetzki, R. Schmid-Fetzer, S.G. Fries, and H.L. Lukas,Z. Metallkd., 85 (11) (1994) in press.
Author information
Authors and Affiliations
Additional information
On leave from Instituto de Física, Universidade Federal do Rio Grande do Sul, Av. Bento Gonçalves 9500, 91501-970 Porto Alegre, RS, Brazil.
Rights and permissions
About this article
Cite this article
Fries, S.G., Lukas, H.L., Konetzki, R. et al. Experimental investigation and thermodynamic optimization of the Y-Cu binary system. JPE 15, 606–614 (1994). https://doi.org/10.1007/BF02647621
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF02647621