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Formation of nitrone in the reaction ofpara-nitroso-N,N-dimethylaniline with tetracyanoethylene

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Abstract

para-Nitroso-N,N-dimethylaniline reacts with tetracyanoethylene to give [4-(dimethyl-amino)phenylimino]malononitrileN-oxide 1 (65%) in addition to [4-(dimethyl-amino)phenylimino]malononitrile 2 (17%). The structures of the products are confirmed by spectral data and chemical transformations.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    D. L. Lipilin, A. M. Churakov, S. L. Ioffe, Yu. A. Strelenko & V. A. Tartakovsky

Authors
  1. D. L. Lipilin
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  2. A. M. Churakov
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  3. S. L. Ioffe
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  4. Yu. A. Strelenko
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  5. V. A. Tartakovsky
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 617–619, March, 1997.

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Lipilin, D.L., Churakov, A.M., Ioffe, S.L. et al. Formation of nitrone in the reaction ofpara-nitroso-N,N-dimethylaniline with tetracyanoethylene. Russ Chem Bull 46, 596–598 (1997). https://doi.org/10.1007/BF02495425

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  • DOI: https://doi.org/10.1007/BF02495425

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