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Alkyl(aryl)oxy derivatives of thulium(III)

  • Organometallic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The reactions of Tml2(DME)3 with phenol andtert-butyl alcohol afforded thulium(III)-alkoxyiodides ROTmI2(DME)2 (R=Ph and But, respectively). Their structures were determined by X-ray analysis. Monoiodides (RO)2 TmI(THF)2 were synthesized from TmI3 (THF)2 and ROH (taken in a ratio of 1∶2). Triphenoxides (RO)3Tm (R=Ph or 2,4,6-But 3C6H2) were prepared by the reactions of the naphthalene thulium complex [C10H8Tm(DME)]2C10H8, with an excess of the corresponding phenol. The iodide catechoxide complex 3,6-But 2C6H2O2TmI(DME)2 was prepared by the reaction of TmI2(DME)3 with 3,6-di-tert-butylbenzoquinone-1,2 or 3,6-di-tert-butylpyrocatechol.

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References

  1. M. N. Bochkarev, I. L. Fedushkin, A. A. Fagin, T. V. Petrovskaya, J. W. Ziller, R. N. R. Bromhall-Dillard, and W. J. Evans,Angew. Chem. Int. Ed. Engl., 1997,35, 133.

    Article  Google Scholar 

  2. M. N. Bochkarev, A. A. Fagin, I. L. Fedushkin, A. A. Trifonov, E. N. Kirillov, I. L. Eremenko, and S. E. Nefedov,Materials Science Forum, 1999.

  3. W. J. Evans, T. J. Boyle, and J. W. Ziller,J. Am. Chem. Soc., 1993,115, 5084.

    Article  CAS  Google Scholar 

  4. W. Gecheng, G. Hanrong, J. Zhongsheng, and S. Qi,Chinese J. Struct. Chem. (Jiegou Huaxue), 1989,8, 61.

    Google Scholar 

  5. S.-H. Lin, Z.-C. Dong, J.-S. Huang, Q.-E. Zhang, and X.-L. Lu,Acta Crystallogr., 1991,C47, 426.

    CAS  Google Scholar 

  6. C. Wenqi, X. Y. Zhongsheng, E. Yuguo, and Y. Guangdi,Inorg. Chim. Acta, 1987,130, 125.

    Article  Google Scholar 

  7. J. Zhongsheng, N. Guojin, H. Ninghai, and C. Wenqi,Chin. J. Appl. Chem. (Yingyong Huaxue), 1989,6, 68.

    Google Scholar 

  8. H. Ning-Hai, L. Yong-Hua, S. Qi, X. Yan, and S. En-Dong,Acta Chim. Sin. (Huaxue Xuebao), 1986,44, 388.

    Google Scholar 

  9. W. J. Evans, I. Bloom, J. W. Grate, L. A. Hughes, W. E. Hunter, and J. L. Atwood,Inorg. Chem., 1985,24, 4620.

    Article  CAS  Google Scholar 

  10. Z. Jin, S. Jin, X. Wang, and W. Chen,Chinese J. Struct. Chem. (Jiegou Huaxue), 1988,7, 181.

    CAS  Google Scholar 

  11. W. J. Evans, J. L. Shreeve, J. W. Ziller, and R. J. Doedens,Inorg. Chem., 1995,34, 576.

    Article  CAS  Google Scholar 

  12. W. J. Evans, J. M. Olofson, and J. W. Ziller,J. Am. Chem. Soc., 1990,112, 2308.

    Article  CAS  Google Scholar 

  13. W. J. Evans, T. S. Gummersheimer, and J. W. Ziller,J. Am. Chem. Soc., 1995,117, 8999.

    Article  CAS  Google Scholar 

  14. R. D. Shannon,Acta Crystallogr., 1976,A32, 751.

    CAS  Google Scholar 

  15. M. N. Bochkarev, L. N. Zakharov, and G. S. Kalinina, inOrganoderivatives of Rare Earth Elements, Kluwer Publishing Co., Dordrecht, 1995, 530.

    Google Scholar 

  16. W. J. Evans, J. M. Olofson, and J. W. Ziller,Inorg. Chem., 1989,28, 4308.

    Article  CAS  Google Scholar 

  17. M. N. Bochkarev, I. L. Fedushkin, A. A. Fagin, H. Schumann, and J. Demtschuk,Chem. Comm., 1997, 1783.

  18. XSCANS Software Users Guide, Version 2.1, Siemens Industial Automation, Inc., Madison (WI), 1994.

  19. R. W. Broach, Argonne National Laboratory, Illinois, 1978.

  20. G. M. Sheldrick,SHELXL, Version 5.0, Software Reference Manual, Siemens Analytical X-Ray Instruments, Inc., Madison (WI), 1994.

    Google Scholar 

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation

    M. N. Bochkarev, A. A. Fagin, I. L. Fedushkin & T. V. Petrovskaya

  2. Chemistry Department, University of California, 92697-2025, Irvine, California, USA

    W. J. Evans, M. A. Greci & J. W. Ziller

Authors
  1. M. N. Bochkarev
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  2. A. A. Fagin
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  3. I. L. Fedushkin
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  4. T. V. Petrovskaya
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  5. W. J. Evans
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  6. M. A. Greci
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  7. J. W. Ziller
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1804–1807, September, 1999.

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Bochkarev, M.N., Fagin, A.A., Fedushkin, I.L. et al. Alkyl(aryl)oxy derivatives of thulium(III). Russ Chem Bull 48, 1782–1785 (1999). https://doi.org/10.1007/BF02494829

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  • DOI: https://doi.org/10.1007/BF02494829

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