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Oxidation of γ-stannyl sulfides by monochloramine CB and hydrogen peroxide

  • Organometallic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The first γ-trimethylstannyl sulfimide, Me3Sn(CH2)3S(=NSO2Ar)C5H11-n, was synthesized by oxidative imination of Me3Sn(CH2)3SC5H11-n with ArSO2(Na)Cl (Ar=C6H4Cl-4). Oxidation of γ-trimethylstannyl sulfimide by an alkaline solution of H2O2 gave γ-trimethylstannyl sulfoximide, Me3Sn(CH2)3S(O)(=NSO2Ar)C5H11-n, and γ-trimethylstannyl sulfone, Me3Sn(CH2)3SO2C5H11-n, the latter compound resulting from hydrolysis of the arylsulfimide group. Oxidation of stannyl sulfide by hydrogen peroxide yielded γ-trimethylstannyl sulfoxide, Me3Sn(CH2)3S(O)C5H11-n (under mild conditions) or γ-trimethylstannyl sulfone (under more severe conditions).

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation

    V. I. Shcherbakov, N. E. Stolyarova & Yu. A. Kurskii

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  1. V. I. Shcherbakov
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  2. N. E. Stolyarova
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  3. Yu. A. Kurskii
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 371–374, February, 1997.

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Shcherbakov, V.I., Stolyarova, N.E. & Kurskii, Y.A. Oxidation of γ-stannyl sulfides by monochloramine CB and hydrogen peroxide. Russ Chem Bull 46, 358–361 (1997). https://doi.org/10.1007/BF02494381

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  • DOI: https://doi.org/10.1007/BF02494381

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