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Interaction of immobilized 2,8,14,20-tetramethyl-4,6,10,12,16,18,22,24-octahydroxycalix[4]arene with Na+, Cs+, and NH4 + ions and organic cations

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The equilibrium in the system water—electrolyte—cross-linked polymer containing immobilized 2,8,14,20-tetramethyl-4,6,10,12,16,18,22,24-octahydroxycalix[4]arene was studied. Immobilized calixarene 1 was shown to form 1∶1, 1∶2, 1∶3, and 1∶4 compounds with inorganic cations (Na+, Cs+, and NH4 +), and with organic cations (hexamethylen-tetramine and β-diethylaminoethylp-aminobenzoate) 1∶1 compounds are formed. The affinity of immobilized calixarene1 increases in the series of cations: hexamethylenetetramine <Na+, Cs+, NH4 +<β-diethylaminoethylp-aminobenzoate.

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Authors and Affiliations

  1. Institute of Carbon Materials Chemistry, Siberian Branch of the Russian Academy of Sciences, 18 Sovetskii prosp., 650099, Kemerovo, Russian Federation

    G. N. Al'tshuler, L. A. Sapozhnikova & L. P. Abramova

Authors
  1. G. N. Al'tshuler
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  2. L. A. Sapozhnikova
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  3. L. P. Abramova
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2214–2216, November, 1998.

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Al'tshuler, G.N., Sapozhnikova, L.A. & Abramova, L.P. Interaction of immobilized 2,8,14,20-tetramethyl-4,6,10,12,16,18,22,24-octahydroxycalix[4]arene with Na+, Cs+, and NH4 + ions and organic cations. Russ Chem Bull 47, 2146–2148 (1998). https://doi.org/10.1007/BF02494269

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  • DOI: https://doi.org/10.1007/BF02494269

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