Skip to main content
SpringerLink
Log in

Hydrogenation of aniline to cyclohexylamine on NaOH-promoted or lanthana supported nickel

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

In the vapor phase, the selectivity of the title reaction could be increased to about 90% by promoting traditional type nickel catalysts with NaOH. The use of strongly basic lanthana as support resulted in 95–99% selectivity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C. L. Thomas:Catalytic Processes and Proven Catalysts, p. 141. Academic Press New York and London 1970.

    Google Scholar 

  2. G. C. Bond:Catalysis by Metals, p. 327. Academic Press London and New York 1962.

    Google Scholar 

  3. G. Debus, J. C. Jungers:Bull. Soc. chim. belges,62, 172 (1953).

    Article  CAS  Google Scholar 

  4. D. V. Sokol'skii, A. Ualikhanova, B. T. Mailyubaev:Zh. Fiz. Khim.,62, 542 (1988).

    Google Scholar 

  5. D. V. Sokol'skii, A. Ualikhanova, A. E. Temirbulatova, B. T. Mailyubaev:Zh. Prikl. Khim.,62, 2626 (1989).

    Google Scholar 

  6. D. V. Sokol'skii, A. Ualikhanova, A. E. Temirbulatova, B. T. Mailyubaev:Zh. Org. Khim.,22, 1693 (1986).

    Google Scholar 

  7. D. V. Sokol'skii, A. Ualikhanova, A. E. Temirbulatova:Zh. Org. Khim.,18, 2078 (1982).

    Google Scholar 

  8. D. V. Sokol'skii, A. Ualikhanova, B.T. Mailyubaev, A. B. Korolev:Zh. Fiz. Khim.,62, 541 (1988).

    Google Scholar 

  9. H. Greenfield:J. Org. Chem.,29, 3082 (1964).

    CAS  Google Scholar 

  10. M. Freifelder, G. R. Stone:J. Am. Chem., Soc.,80, 5378 (1958).

    Google Scholar 

  11. M. Freifelder, G. R. Stone:J. Org. Chem.,27, 3568 (1962).

    CAS  Google Scholar 

  12. H. A. Smith, W. C. Bedoit:J. Phys. Colloid Chem.,55, 1085 (1951).

    Article  CAS  Google Scholar 

  13. E. L. Pitara, B. N'Zemba, J. Barbier, F. Barbot, Miginiac:J. Mol. Catal. A. Chem.,106, 235 (1996).

    Article  CAS  Google Scholar 

  14. J. M. Devereux, K. R. Payne, E. R. A. Peeling:J. Chem. Soc., 2845 (1957).

  15. C. Kemball, R. L. Moss:Trans. Faraday Soc. 56, 154 (1960).

    Article  Google Scholar 

  16. V. Vishwanathan, S. Narayanan:J. Chem. Soc., Chem. Commun.,78 (1990).

  17. V. Vishwanathan, S. Narayanan:Indian J. Chem., Sect. A,30A, 679 (1991).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Research Laboratory of Materials and Environmental Chemistry Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, 1025, Budapest

    G. Mink & L. Horváth

Authors
  1. G. Mink
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. Horváth
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mink, G., Horváth, L. Hydrogenation of aniline to cyclohexylamine on NaOH-promoted or lanthana supported nickel. React Kinet Catal Lett 65, 59–65 (1998). https://doi.org/10.1007/BF02475316

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02475316

Keywords

Search

Navigation