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Volatile mixed-ligand complexes of bis(diisobutyldithiocarbamato)zinc with 1,10-phenanthroline, 2,2′-bipyridyl, and 4,4′-bipyridyl. Crystal and molecular structure of the binuclear complex [Zn2(C10H8N2){(i-C4H9)2NCS2∼4]

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Abstract

Mixed-ligand complexes ZhPhen(i-Bu2Dtc)2, Zn(2,2′-Bipy)(i-Bu2Dtc)2, and Zn2(4,4′-Bipy)(i-Bu2Dtc)4, where i-Bu2Dtc=(i-C4H9)2NCS −2 , have been synthesized. The structure of Zn2(4,4′-Bipy)(i-Bu2Dtc)4 was determined by X-ray diffraction analysis; it consists of centrosymmetric binuclear molecules with trigonal-bipyramidal coordination of the central Zn atom. When heated in vacuum, the compounds quantitatively sublimate or evaporate. Thermal decomposition of the compounds in air (350°C) gives α-ZnS.

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Authors
  1. S. M. Zemskova
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  2. L. A. Glinskaya
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  3. R. F. Klevtsova
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  4. V. B. Durasov
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  5. S. A. Gromilov
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  6. S. V. Larionov
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Additional information

Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 37, No. 6, pp. 1114–1121, November–December, 1996.

Translated by L. Smolina

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Zemskova, S.M., Glinskaya, L.A., Klevtsova, R.F. et al. Volatile mixed-ligand complexes of bis(diisobutyldithiocarbamato)zinc with 1,10-phenanthroline, 2,2′-bipyridyl, and 4,4′-bipyridyl. Crystal and molecular structure of the binuclear complex [Zn2(C10H8N2){(i-C4H9)2NCS2∼4]. J Struct Chem 37, 941–947 (1996). https://doi.org/10.1007/BF02439079

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  • DOI: https://doi.org/10.1007/BF02439079

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