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Oxygen ion diffusion in perovskite-type oxides determined by permeation and by relaxation measurements

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Abstract

Oxygen ion diffusion in oxides of the perovskite-type structure was determined by two methods of measurement: i) stepwise change of temperature or oxygen partial pressure of the gaseous environment of a ceramic sample, and measurement of the relaxation of electrical conductivity or oxygen content, ii) oxygen permeation through a gas dense oxide ceramic pellet from air to argon. The experimental problems and sources of errors, calculation methods of chemical diffusion coefficients and oxide ionic conductivities from these two modes of investigation are discussed. The comparison of relaxation and permeation measurements on 10 oxides of the type A1−aA′aM1−bM′bO3−σ (A=La, Pr, Ce; A′=Sr, Ca; M=Mn, Fe; M′=Co, Ni) show advantages of the relaxation method in relation to the experimental performance and possible errors.

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References

  1. Y. Teraoka, T. Nobunaga, N. Yamazoe, Chem. Letters 503–506 (1988).

  2. Y. Teraoka, T. Nobunaga, K. Okamoto, N. Miura, N. Yamazoe, Solid State Ionics48, 207 (1991).

    Article  CAS  Google Scholar 

  3. W.J. Weber, J.W. Stevenson, T.R. Armstrong, L.R. Pederson, Processing and electrochemical properties of mixed conducting La1−xAxCo1−yFeyO3−δ (A=Sr,Ca), in: Mater. Res. Soc. Symp. Proc. (G.-A. Nazri, J.-M. Taracson, M.S. Schreiber, Eds.) Mater. Res. Soc. Pittsburgh369, 395–400 (1995).

    CAS  Google Scholar 

  4. Sh. Li, W. Jin, N. Xu, J. Shi, Solid State Ionics124, 161 (1999).

    Article  CAS  Google Scholar 

  5. J.E. ten Elshof, H.J.M. Bouwmeester, H. Verweij, Appl. Catalysis A: General130, 195 (1995).

    Google Scholar 

  6. O.F. Kononchuk, T. Norby, P. Kofstad, Phase Trans.58, 145 (1996).

    CAS  Google Scholar 

  7. H. Kruidhof, H.J.M. Bouwmeester, R.H.E. van Doorn, A.J. Burggraaf, Solid State Ionics63–65, 816 (1993).

    Google Scholar 

  8. L. Qiu, T.H. Lee, L.-M. Liu, Y.L. Yang, A.J. Jacobson, Solid State Ionics76, 321 (1995).

    Article  CAS  Google Scholar 

  9. V.V. Vashook, S.I. Pytlev, O.P. Ol‘shevskaya, et al., Inorganic Materials36, 849 (2000).

    Google Scholar 

  10. H. Ullmann, N. Trofimenko, F. Tietz, D. Stover, A. Ahmad-Khanlou, Solid State Ionics138, 79 (2000).

    Article  CAS  Google Scholar 

  11. J.M. Paulsen, Doctor Thesis, TU Dresden, Fak. Math. Nat., 1997.

  12. N.E. Trofimenko, H. Ullmann, J. European Ceramic Soc.20, 1241 (2000).

    CAS  Google Scholar 

  13. V.V. Kharton, A.P. Viskup, E.N. Naumovich, V.N. Tikhonovich, Mater. Res. Bull.34, 1311 (1999).

    CAS  Google Scholar 

  14. W. Weppner, R.A. Huggins, Ann. Rev. Mater. Sci.8, 269 (1978).

    CAS  Google Scholar 

  15. The CRC handbook of solid state electrochemistry / Edited by P.J.Gellings and H.J.M. Bouwmeester // CRC Press, Boca Raton, New York, London, Tokio 1997, p. 481–553.

  16. Ch. Ftikos, S. Carter, B.C.H. Steele, J. Europ. Ceram. Soc.12, 79 (1993).

    CAS  Google Scholar 

  17. V.V. Kharton, E.N. Naumovich, A.V. Kovalevsky et al., Solid State Ionics138, 135 (2000).

    Article  CAS  Google Scholar 

  18. V.N. Chebotin, Chemical diffusion in solids. Moscow: Nauka, 1989, p. 208.

    Google Scholar 

  19. L.E. Gurevich, Fundarnentals of physical kinetics, Moskov, Gostechteorizdat, 1940, p. 243.

  20. H. Rickert, Electrochemistry of Solids: An introduction, Springer, 1982, p. 240.

  21. V.N. Chebotin, Dokladi Akademii Nauk SSSR,2, 674 (1982).

    Google Scholar 

  22. K. Teske, H. Ullmann, N. Trofimenko, J. Thermal Analysis49, 1211 (1997).

    CAS  Google Scholar 

  23. H. Ullmann, N. Trofimenko, Solid State Ionics119, 1 (1999).

    Article  CAS  Google Scholar 

  24. K. Kishio, Y. Yamozone et al., Journal of Solid State Chem.82, 192 (1989).

    CAS  Google Scholar 

  25. Y. Teraoka, H.M. Zhang, K. Okamoto, N. Yamazoe, Mat. Res. Bull.23, 51 (1988).

    Article  CAS  Google Scholar 

  26. J.W. Stevenson, T.R. Armstrong, R.D. Carneim, L.R. Pederson, W.J. Weber, J. Electrochem. Soc.143, 2722 (1996).

    CAS  Google Scholar 

  27. S. Sekido, H. Tachibana, Y. Yamamura, T. Kambara, Solid State Ionics37, 253 (1990).

    Article  CAS  Google Scholar 

  28. C.H. Chen, H.J.M. Bouwmeester, R.H.E. van Doorn, H. Kruidhof, A.J. Burggraaf, Solid State Ionics98, 7 (1997).

    Article  CAS  Google Scholar 

  29. W. Zipprich, H.-D. Wiemhofer, Solid State Ionics135, 699 (2000).

    Article  CAS  Google Scholar 

  30. S.B. Adler, Solid State Ionics135, 603 (2000).

    Article  CAS  Google Scholar 

  31. V.V. Kharton, E. Naumovich, A.A. Vecher, A. Nikolaev, J. Solid State Chemistry120, 128 (1995).

    CAS  Google Scholar 

  32. M.H.R. Lankhorst, Doctor Thesis, University of Enschede, Netherlands, 1997.

  33. S. Diethelm, A. Closset, J. Van Herle, A.J. McEvoy, K. Nisancioglu, Solid State Ionics135, 613 (2000).

    Article  CAS  Google Scholar 

  34. S. Aasland, I.L. Tangen, K. Wiik, R. Odegard, Solid State Ionics135, 713 (2000).

    Article  CAS  Google Scholar 

  35. T. Bak, J. Novotny, M. Rekas, C.C. Sorrell, E.R. Vance, Solid State Ionics135, 557 (2000).

    CAS  Google Scholar 

  36. M. Suzuki, H. Sasaki, A. Kajimura, Solid State Ionics96, 83 (1997).

    Article  CAS  Google Scholar 

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Vashook, V.V., Al Daroukh, M. & Ullmann, H. Oxygen ion diffusion in perovskite-type oxides determined by permeation and by relaxation measurements. Ionics 7, 59–66 (2001). https://doi.org/10.1007/BF02375467

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