Summary
A rapid method is described for the determination of hydrocarbon groups in coal liquids. Analysis is carried out by high-performance liquid chromatography on a LiChrosorb NH2 column with n-hexane as the mobile phase. The separation is controlled only by the number of double bonds in a given hydrocarbon molecule. It is essentially independent of the molecular mass for a large variety of compounds investigated. Example of the separation of hydrogenated derivatives of anthracene and of a coal liquid fraction are presented.
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References
J. C. Suatoni andR. E. Swab, J. Chrom. Sci.13, 361 (1975).
ASTM Standards D-1319, “Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption”, Part 17, 497 (1970).
D. M. Jewell, E. W. Albaugh, B. E. Davis andR. G. Ruberto, I. & E.C. Fundamentals13, 278 (1974).
M. Martin, J. Lohéac andG. Guiochon, Chromatographia5, 33 (1972).
J. F. Schabron, R. J. Hurtubise andF. Silver, Anal. Chem.49, 2253 (1977).
D. W. Grant andR. B. Meiris, J. Chromatogr.142, 339 (1977).
G. P. Blümer andM. Zander, Fresenius Z. Anal. Chem.288, 277 (1977).
S. A. Wise, S. N. Chesler, H. S. Hertz, L. R. Hilpert andW. E. May, Anal. Chem.49, 2306 (1977).
S. C. F. Robinson, Chromatographia12, 439 (1979).
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Liphard, K.G. Hydrocarbon group-type analysis of coal liquids by high-performance liquid chromatography. Chromatographia 13, 603–606 (1980). https://doi.org/10.1007/BF02302459
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DOI: https://doi.org/10.1007/BF02302459