Summary
To obtain an adequate separation of the products of this reaction, which consisted of a mixture of chloro derivatives in solution in CCl4, with concentrations less than 0.1%, the method of programmed temperature (100–160°C) gas chromatography was applied. A column containing 30% DC-11 silicone on Chromosorb W, and ionization detectors were used. Five products (CH2Cl2, CHCl3, C2Cl4, C2HCl5 and C2Cl6) were identified. Quantitative determination of two of them (CHCl3 and C2Cl6) was made, using calibration curves.
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Literature
Molinari, M. A., Videla, G. J., XI Cong. Latinoamericano de Química, Santiago, Chile, 1972. Resumen VI-78.
Rojo, E. A., Lires, O. A., Ibid XI Cong. Latinoamericano de Química, Santiago, Chile, 1972. resumen II-5.
Otolenghi, M., Stein, G., Radiation Res.14, 281 (1961).
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Hild, S.L.E., Molinari, M.A. & Videla, G.J. Gas chromatographic analysis of the products from the gamma-induced reaction between H2 and CCl4 . Chromatographia 6, 440–442 (1973). https://doi.org/10.1007/BF02281024
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DOI: https://doi.org/10.1007/BF02281024