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Electronic state of the active site of A V−P−O/SiO2 catalyst in oxidation of chlorine-containing hydrocarbons

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Abstract

V4+ ions in slightly associated states are supposed to play the role of V−P−O/SiO2 active sites. V4+ ions are reduced to V3+ during deactivation of the V−P−O/SiO2 catalyst.

Abstract

В качестве активного центра V−P−O/SiO2 катализатора предполагаются ионы V4+ в слабо ассоциированном состоянии. В процессе дезактивации V−P−O/SiO2 катализатора происходит восстановление V4+ до состояния V3+.

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Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, USSR

    A. G. Agazade, G. A. Dergaleva, V. F. Anufrienko, A. A. Davydov, T. N. Shakhtakhtinskii & A. D. Efendiev

  2. Institute of Theoretical Problems of Chemical Technology, Baku, USSR

    A. G. Agazade, G. A. Dergaleva, V. F. Anufrienko, A. A. Davydov, T. N. Shakhtakhtinskii & A. D. Efendiev

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  1. A. G. Agazade
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  2. G. A. Dergaleva
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  3. V. F. Anufrienko
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  4. A. A. Davydov
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  5. T. N. Shakhtakhtinskii
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  6. A. D. Efendiev
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Agazade, A.G., Dergaleva, G.A., Anufrienko, V.F. et al. Electronic state of the active site of A V−P−O/SiO2 catalyst in oxidation of chlorine-containing hydrocarbons. React Kinet Catal Lett 40, 83–88 (1989). https://doi.org/10.1007/BF02235143

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  • DOI: https://doi.org/10.1007/BF02235143

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