Abstract
The influence of γ-irradiation upto 200 Mrad on the thermal decomposition of barium bromate has been studied in the temperature range 553–583 K. The fraction decomposed /α/-time /t/ characteristics for irradiated barium bromate exhibit stages, viz. initial gas and decay stages. Irradiation shortens the induction period conforming to the relation I=C1−C2 lg dose. All experimental data for induction period are tested against the values obtained from the theoretical calculations by making use of this induction-period dose relation. The topochemical aspect of the validity of the above relation has been considered to be due to the linear growth of nuclei during irradiation and subsequent exponential growth during the induction period.
Similar content being viewed by others
References
S. D. Bhattamisra, S. R. Mohanty,J. Inorg. Nucl. Chem., 39 /1977/ 2103.
B. Jena, S. R. Mohanty, M. Satapathy,Ind. J. Chem., 19A /1980/ 1139.
P. W. M. Jacobs, F. C. Tompkins, Chemistry of Solid State, Ed. W. E. Garner, Butterworths Scientific Publications, London, 1955.
F. C. Tompkins, Reactivity of Solids, Ed. N. B. Hannay, Plenum Press, New York, 1976.
S. D. Bhattamisra, S. R. Mohanty,Radiat. Effects, 29 /1976/ 41.
F. Solymosi, Structure, and Stability of Salts of Halogen Oxyacids in the Solid Phase, J. Wiley, London, 1977.
E. G. Prout, M. J. Sole,J. Inorg. Nucl. Chem., 9 /1959/ 232.
P. W. Levy, P. J. Herley,J. Phys. Chem., 75 /1971/ 191.
S. Fogler, D. Lawson,J. Phys. Chem., 74 /1970/ 1637.
D. W. Pearce, R. G. Russell, Inorganic Synthesis, Ed. W. C. Fernelius, McGraw-Hill, New York, 1946.
J. W. Mellor, A Comprehensive Treatise of Inorganic and Theoretical Chemistry, Longmans, London, 1952.
E. G. Prout, F. C. Tompkins,Trans. Faraday Soc., 40 /1944/ 488.
E. R. Johnson, The Radiation-induced Decomposition of Inorganic Molecular Ions, Gordon and Breach, New York, 1970.
D. Bhatta, S. R. Mohanty, K. C. Samantray,Radiochim. Acta, 28 /1981/ 13.
N. Bohidar, S. R. Mohanty,Radiochim. Acta, 27 /1980/ 19.
N. Bohidar, S. R. Mohanty,Ind. J. Chem., 19A /1980/ 1058.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bohidar, N., Jena, B. & Mohanty, S.R. Study of the induction period of the thermal decomposition of irradiated barium bromate. Journal of Radioanalytical and Nuclear Chemistry Letters 95, 291–299 (1985). https://doi.org/10.1007/BF02168026
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02168026