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Molybdate polymerisation studied by perturbed angular correlation

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Abstract

We determined the average nuclear quadrupole interaction (NQI) at99tc in frozen aqueous molybdate solutions at 77K as a function of pH. The polymerisation shows up clearly in the titration curve at pH

6.5 and leads to a dramatic increase of the NQI.

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Authors and Affiliations

  1. Walther Meissner Institut für Tieftemperaturforschung der Bayerischen Akademie der Wissenschaften, 8046, Garching, FRG

    A. Lerf, C. Vogdt, T. Butz, A. M. M. Eid & H. Knözinger

  2. Institut für Physikalische Chemie der Universität, 8000, München, FRG

    C. Vogdt & H. Knözinger

  3. Physik-Department der Technischen Universität, 8046, Garching, FRG

    T. Butz & A. M. M. Eid

Authors
  1. A. Lerf
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  2. C. Vogdt
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  3. T. Butz
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  4. A. M. M. Eid
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  5. H. Knözinger
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on leave from Tanta University, Egypt

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Lerf, A., Vogdt, C., Butz, T. et al. Molybdate polymerisation studied by perturbed angular correlation. Hyperfine Interact 16, 921–924 (1983). https://doi.org/10.1007/BF02147394

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  • DOI: https://doi.org/10.1007/BF02147394

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