Skip to main content
SpringerLink
Log in

The activity of Ni/AlPO4, Ni/AlPO4−Al2O3 and Ni/AlPO4−SiO2 catalysts in the hydrogenation of e-cinnamaldehyde

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Liquid-phase catalytic hydrogenatio of E-cinnamaldehyde was carried out by using new supported nickel catalysts (Ni/AlPO4, Ni/AlPO4−Al2O3 and Ni/AlPO4−SiO2) in methanol as solvent under low hydrogen pressure (4.1 bar) and 298 K. The kinetic orders are zero in H2 and aldehyde. The selectivity to the hydrogenaton of the C=C double bond is very high (>99%)

Abstract

Каталитическое жидкофазное гидрирование Е-коричного альдегида производилось при использовании новых никелебых катализаторов на носителях (Ni/AlPO4, Ni/AlPO4−Al2O3 и Ni/AlPO4−SiO2) в метаноле как растворителе при низком давлении водорода (4,1 бар) и 298 К. Кинетический порядок по H2 и альдегиду является нуяевым. Селективность гидрирования двойной связи C−C очень бысока (>90%).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. E. Pascoe, J. F. Stenberg: Catalysis in Organic Syntheses, p. 1. Academic Press, New York 1980.

    Google Scholar 

  2. F. Straus, H. Grindel: Liebigs, Ann. Chem.,439, 276 (1924).

    Google Scholar 

  3. M. T. Bogert, G. Powell: J. Amer. Chem. Soc.,53, 2747 (1931)

    Google Scholar 

  4. T. W. Russel, R. C. Hoy: J. Org. Chem.,36, 2018 (1971).

    Google Scholar 

  5. W. S. Millman, G. V. Smith: Caalysis in Organic Syntheses, p. 33. Academic Press, New York, 1977.

    Google Scholar 

  6. A. Alberola, J. M. Marinas: An. Quim.,65, 1007 (1969).

    Google Scholar 

  7. J. M. Campelo, J. M. Marinas, R. Perez-Ossorio: Proc. 5th Ibero-American Symposium on Catalysis, p. 84. Lisbon, 1976.

  8. C. Jimenez, J. M. Marinas, R. Perez-Ossorio, J. V. Sinisterra: An. Quim.,73, 1164 (1977).

    Google Scholar 

  9. D. Luna: Ph. d. Thesis, Cordoba Univ., Spain, 1981.

  10. P. M. Rylander, N. Himelstein, M. Kilroy: Engelhard Ind. Tech. Bull.,4, 95 (1963).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Organic Chemistry, Cordoba Universeioty, Cordoba, Spain

    J. M. Campelo, A. Garcia, D. Luna & J. M. Marinas

Authors
  1. J. M. Campelo
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Garcia
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. Luna
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J. M. Marinas
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Campelo, J.M., Garcia, A., Luna, D. et al. The activity of Ni/AlPO4, Ni/AlPO4−Al2O3 and Ni/AlPO4−SiO2 catalysts in the hydrogenation of e-cinnamaldehyde. React Kinet Catal Lett 18, 325–328 (1981). https://doi.org/10.1007/BF02065616

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02065616

Keywords

Search

Navigation