Abstract
N,N′-Bis(nitroacetyl)diamines were synthesized for the first time by the reaction of methyl nitroacetate with aliphatic diamines in H2O or EtOH in the presence of pyridine or imidazole. In the case of 1,2-ethylenediamine, theN-mononitroacetyl derivative was isolated as an intermediate product.
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References
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Translated fromIzvestiva Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2363–2366, September, 1996
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Lyapkalo, I.M., Ioffe, S.L., Strelenko, Y.A. et al. Acylation of aliphatic diamines with methyl nitroacetate. Russ Chem Bull 45, 2245–2247 (1996). https://doi.org/10.1007/BF01430754
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DOI: https://doi.org/10.1007/BF01430754