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Crystal and molecular structure of dichlorofluoroacetamide

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Abstract

The crystal structure of dichlorofluoroacetamide has been determined from three-dimensional counter data, and refined by full-matrix least-squares techniques. The crystals belong to the monoclinic space groupP21 /c and have the unit-cell parametersa = 10.207(4),b = 5.729(2),c = 9.971(4) Å, β = 105.21(8) °, andD x = 1.72 g cm-3. The structural refinement gave a finalR factor of 0.067 from 440 observed reflections. The compound has nearly equal disorder of the -Cl2F moiety about the C-C bond axis with occupancy factors of the two fragments being 0.48 and 0.52.

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References

  • Busing, W. R., Martin, K. O., and Levy, H. A. (1962) ORFLS. Report ORNL-TM-305, Oak Ridge National Laboratory, Oak Ridge, Tennessee.

    Google Scholar 

  • Cromer, D. T., and Waber, J. T. (1965)Acta Cryst. 18, 104–109.

    Google Scholar 

  • Cruickshank, D. W. J., Jones, D. W., and Walker, G. (1964)J. Chem. Soc., 1303–1314.

  • Germain, G., Main, P., and Woolfson, M. M., (1971)Acta Cryst. A 27, 368–376.

    Google Scholar 

  • Griffin, R. G., Ellett, J. D., Jr., Mehring, M., Bullitt, J. G., and Waugh, J. S. (1972)J. Chem. Phys. 57, 2147–2155.

    Google Scholar 

  • Hughes, D. O., and Small, R. W. H. (1962)Acta Cryst. 15, 933–940.

    Google Scholar 

  • Hughes, D. O., and Small, R. W. H. (1972)Acta Cryst. B 28, 2520–2524.

    Google Scholar 

  • International Tables for X-ray Crystallography (1974) Vol. III, (Kynoch Press, Birmingham, England), p. 202.

  • Kalyanaraman, B., Kispert, L. D., and Atwood, J. L. (1976)J. Cryst. Mol. Struct. 6, 311–316.

    Google Scholar 

  • Kalyanaraman, B., Kispert, L. D., and Atwood, J. L. (1978)Acta Cryst. B 34, 1131–1136.

    Google Scholar 

  • Kasper, J. S., and Interrante, L. V. (1976)Acta Cryst. B 32, 2914–2916.

    Google Scholar 

  • Pace, D. (1979) Ph.D. Dissertation, The University of Alabama.

  • Wei, K. T., and Ward, D. L. (1976)Acta Cryst. B 32, 2768–2773.

    Google Scholar 

  • Yokozeki, A., and Bauer, S. H. (1975)Top. Curr. Chem. 53, 71–119.

    Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, The University of Alabama, 35486, Tuscaloosa, Alabama

    Dale Pace, William E. Hunter, Riz Shakir, Lowell D. Kispert & Jerry L. Atwood

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  1. Dale Pace
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  2. William E. Hunter
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  3. Riz Shakir
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  4. Lowell D. Kispert
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  5. Jerry L. Atwood
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Pace, D., Hunter, W.E., Shakir, R. et al. Crystal and molecular structure of dichlorofluoroacetamide. Journal of Crystal and Molecular Structure 10, 115–121 (1980). https://doi.org/10.1007/BF01237623

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  • DOI: https://doi.org/10.1007/BF01237623

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