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Synthesis and reactions of oxygen-containing organosilicon compounds communication 6. Preparation of secondary dialkyl(or aryl)chlorosilanes and dialkyl(or aryl)silanols and some of their reactions

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Dialkyl(or aryl)silanols containing silicon-attached hydrogen R2Si(H)OH and tetraalkyl(or aryl) disiloxanes of general formula

    were synthesized and characterized for the first time, Diethylethylisobutyl-, and ethylphenyl-silanols and symmetrical tetraethyl-, diethyldiisobutyl-, and diethyldiphenyldisiloxanes were prepared.

  2. 2.

    Chlorodiethyl-, chloroethylisobutyl-, and chloroethylphenyl-silanes were prepared for the first time.

  3. 3.

    It was shown dialkyl(or aryl)chlorosilanes (the example taken was chlorodiethylsilane) react with ammonia with formation of disilazanes

    . When hydrolyzed, 1,1,3,3-tetra ethyldisilazane gives diethylsilanol and 1,1,3,3-tetraethyldisiloxane.

  4. 4.

    When dialkylsilanols react with vinyl ethers, organosilicon acetals of the following structure are formed:

    (R1 and R2 are alkyl or aryl groups).

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Literature cited

  1. K. A. Andrianov and D. A. Kochkin, Authors' Certificate No. 71050, 1947; Authors' Certificate No. 9517, 1949; Bull. Inventions 1948, No. 4, 16.

  2. M. F. Shostakovsky, I. A. Shikhiev, and D. A. Kochkin, Bull. Acad. Sci. USSR, Div. Chem. Sci, 1953, 941 ( T.p. 837).

  3. M. F. Shostakovsky and D. A. Kochkin, Proc. Acad. Sci. USSR 95, No. 4, 821 (1954).

  4. M. F. Shostakovsky, K. A. Andrianov, I. A. Shikhiev, and D, A, Kochkin, Proc. Acad. Sci. USSR 93, 641(1953).

  5. H. I. Emeleus and S. R. Robinson, J. Chem. Soc. 1947, 1592.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    M. F. Shostakovsky, D. A. Kochkin & V. M. Rogov

Authors
  1. M. F. Shostakovsky
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  2. D. A. Kochkin
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  3. V. M. Rogov
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Shostakovsky, M.F., Kochkin, D.A. & Rogov, V.M. Synthesis and reactions of oxygen-containing organosilicon compounds communication 6. Preparation of secondary dialkyl(or aryl)chlorosilanes and dialkyl(or aryl)silanols and some of their reactions. Russ Chem Bull 5, 1079–1085 (1956). https://doi.org/10.1007/BF01177360

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  • DOI: https://doi.org/10.1007/BF01177360

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