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Isomerization of diethoxyphosphorylalkene oxides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Diethoxyphosphorylpropylene oxide when heated with ZnCl2 is isomerized to phosphonoacetone and diethyl isopropenyl phosphate.

  2. 2.

    The diethoxyphosphorylbutylene and diethoxyphosphorylcyclopentene oxides are isomerized to methylphosphonoacetone and phosphonocyelopentanone, respectively.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1146–1148, May, 1967.

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Arbuzov, B.A., Polezhaeva, N.A. & Vinogradova, V.S. Isomerization of diethoxyphosphorylalkene oxides. Russ Chem Bull 16, 1110–1111 (1967). https://doi.org/10.1007/BF01176049

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  • DOI: https://doi.org/10.1007/BF01176049

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