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Investigation of hydrogen bonding in α-aminonicotine by the method of comparing infrared absorption spectra

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

Investigation of aminonicotines and their hydrochlorides by the method of infrared absorption spectra showed.

  1. 1.

    The presence of an intramolecular hydrogen bond in α-aminonicotine. The wave number for the valancy vibration of the N-H link participating in the intramolecular hydrogen bond is 3325 cm−1 in the crystal and 3290 cm−1 in carbon tetrachloride solution.

  2. 2.

    The intramolecular bond in α-aminonicotine is broken when hydrogen halide or methyl iodide adds to the pyrrolidine nitrogen.

  3. 3.

    The hydrochlorides of α- and α-aminonicotines have similar spectra.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    Ya. L. Goldfarb, M. S. Kondakova & D. N. Shigoria

  2. L. Ya. Karpov Physicochemical Institute, USSR

    Ya. L. Goldfarb, M. S. Kondakova & D. N. Shigoria

Authors
  1. Ya. L. Goldfarb
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  2. M. S. Kondakova
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  3. D. N. Shigoria
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Goldfarb, Y.L., Kondakova, M.S. & Shigoria, D.N. Investigation of hydrogen bonding in α-aminonicotine by the method of comparing infrared absorption spectra. Russ Chem Bull 5, 323–326 (1956). https://doi.org/10.1007/BF01172452

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  • DOI: https://doi.org/10.1007/BF01172452

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