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Some reactions of the amino group of 1,1,1-triethylsilylamine

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    In a study of the reactions of 1,1,1-triethylsilylamine and its N-alkyl derivatives (including the new compounds 1,1,1-triethyl-N-methylsilylamine and 1,1,1-triethyl-N,N-dimethylsilylamine) it was shown that treatment of these compounds with water causes the amino group to be replaced by hydroxyl and treatment with alcohols brings about replacement by alkoxyl.

  2. 2.

    The reaction of silylamines with aliphatic alcohols was applied in the synthesis of new compounds, namely alkoxytriethylsilanes (C2H5)3SiOR (R = propyl, isopropyl, butyl, isobutyl, isopentyl, and octyl).

  3. 3.

    It was shown that silylamines are of fairly good thermal stability and are not decomposed by long boiling.

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Andrianov, K.A., Golubtsov, S.A. & Semenova, E.A. Some reactions of the amino group of 1,1,1-triethylsilylamine. Russ Chem Bull 7, 41–46 (1958). https://doi.org/10.1007/BF01170859

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  • DOI: https://doi.org/10.1007/BF01170859

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