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Mechanism of the reaction between 2,6-diphenyl-1,4-benzoquinone and alphatic diamines

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The existence of rigid and labile donor-acceptor complexes in the 2,6-diphenyl-1,4-benzoquinone-ethylenediamine system, the stability of which is determined by the rate of consumption of the 2,6-diphenyl-1,4-benzoquinone, has been demonstrated by means of ESR spectroscopy.

  2. 2.

    The fact that cyclohexadienone is formed in the 1,4-addition of ethylenediamine to 2,6-diphenyl-1,4-benzoquinone has been confirmed by NMR spectroscopy.

  3. 3.

    The nature of the hydrocarbon fragment of the diamine has a substantial effect on the direction of its reaction with 2,6-diphenyl-1,4-benzoquinone.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    B. D. Sviridov, M. V. Serdobov, V. I. Porkhun & R. V. Poponova

  2. All-Union Scientific Research Institute for Chemical Reagents and Ultrahigh Purity Chemicals, Moscow

    B. D. Sviridov, M. V. Serdobov, V. I. Porkhun & R. V. Poponova

  3. Volgograd Polytechnic Institute, USSR

    B. D. Sviridov, M. V. Serdobov, V. I. Porkhun & R. V. Poponova

Authors
  1. B. D. Sviridov
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  2. M. V. Serdobov
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  3. V. I. Porkhun
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  4. R. V. Poponova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, pp. 105–112, January, 1983.

The authors express their thanks to A. K. Ryzhankova for developing a method for the preparation of absolute ethylenediamine.

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Sviridov, B.D., Serdobov, M.V., Porkhun, V.I. et al. Mechanism of the reaction between 2,6-diphenyl-1,4-benzoquinone and alphatic diamines. Russ Chem Bull 32, 88–94 (1983). https://doi.org/10.1007/BF01167766

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  • DOI: https://doi.org/10.1007/BF01167766

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