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Reaction of allyl chloride with cyclohexane and methylcylcohexane initiated by tertiary butyl peroxide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Tertiary butyl peroxide initiates the addition of cyclohexane and methylcyclohexane to allyl chloride. In the reaction with methylcyclohexane a mixture of isomers with the substituents in different positions is formed.

  2. 2.

    Allylcyclanes are formed in addition to chloropropylcycloalkanes.

  3. 3.

    The degree of conversion of the allyl chloride and the yield of the addition product in the reaction with methylcyclohexane are twice as great as with cyclohexane.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    L. Kh. Freidlin, N. M. Nazarova & D. L. Badalova

Authors
  1. L. Kh. Freidlin
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  2. N. M. Nazarova
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  3. D. L. Badalova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1481–1483, August, 1966.

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Freidlin, L.K., Nazarova, N.M. & Badalova, D.L. Reaction of allyl chloride with cyclohexane and methylcylcohexane initiated by tertiary butyl peroxide. Russ Chem Bull 15, 1427–1429 (1966). https://doi.org/10.1007/BF01151394

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  • DOI: https://doi.org/10.1007/BF01151394

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