Conclusions
-
1.
The reaction of perfluoro-2-butyne with chlorine and bromine fluorosulfates takes place in steps with intermediate formation of the appropriate unsaturated fluorosulfates.
-
2.
In the instance of perfluorobutyne stereospecificity is established on addition of chlorine and bromine fluorosulfates to multiple carbon-carbon bonds of unsaturated fluoroorganic compounds.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
A. V. Fokin, Yu. N. Studnev, L. D. Kuznetsova, and I. N. Krotovich, Usp. Khim.,51, 1258 (1982).
A. V. Fokin, Yu. N. Studnev, A. I. Rapkin and I. N. Krotovich, Izv. Nauk SSSR, Ser Khim., 2374 (1981).
J. W. Emsley, J. Feeney, and L. H. Sutcliffe, High Resolution Nuclear Magnetic Resonance Spectroscopy, Vol. 2, Pergamon, New York (1966).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1094–1097, May, 1985.
Rights and permissions
About this article
Cite this article
Fokin, A.V., Studnev, Y.N., Rapkin, A.I. et al. Reaction of halogen fluorosulfates with perfluro-2-butyne. Russ Chem Bull 34, 998–1001 (1985). https://doi.org/10.1007/BF01142789
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01142789