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Viscosities of nonelectrolyte liquid mixtures. II. Binary mixtures ofn-hexane with alkanoates and bromoalkanoates

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Abstract

Viscosity measurements are reported for mixtures of ethyl ethanoate, ethyl propionate, ethyl butyrate, ethyl-2-bromopropionate, ethyl-3-bromopropionate, ethyl-2-bromobutyrate, and ethyl-4-bromobutyrate withn-hexane at 303.15 K. The viscosity data have been correlated with equations of Grunberg and Nissan, of McAllister, and of Auslaender. Furthermore, excess Gibbs energies of activationΔG *E of viscous flow have been calculated with Eyring's theory of absolute reaction rates and values ofΔG *E for the present binary mixtures have been explained in terms of the dipole-dipole interaction in alkanoates and the intramolecular Br...O interaction in bromoalkanoates.

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  1. Department of Chemistry, South Gujarat University, 395007, Surat, India

    S. L. Oswal & J. P. Dave

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  1. S. L. Oswal
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  2. J. P. Dave
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Oswal, S.L., Dave, J.P. Viscosities of nonelectrolyte liquid mixtures. II. Binary mixtures ofn-hexane with alkanoates and bromoalkanoates. Int J Thermophys 13, 943–955 (1992). https://doi.org/10.1007/BF01141208

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  • DOI: https://doi.org/10.1007/BF01141208

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