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An n.m.r. study on displacements from platinum(II) complexes by dimethylsulphoxide

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Summary

Substitutions of platinum(II) complexes with nitrogen donors by the soft sulphur donor dimethylsulphoxide (DMSO) were studied by n.m.r. spectroscopy and quantum-mechanical calculations.

The results indicate that the softness of halide as well as the affinities of the displaced ligands influence the substitution processes.

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Authors and Affiliations

  1. Dipartimento di Scienze Chimiche, via Ospedale 72, 09124, Cagliari, Italy

    Mariano Casu & Adolfo Lai

  2. Istituto di Chimica Organica, via Ospedale 72, 09124, Cagliari, Italy

    Gioanna Gelli

  3. Inorganica e Analitica, Istituto di Chimica Generale, via Ospedale 72, 09124, Cagliari, Italy

    Gustavo Ponticelli

  4. N. S. Kurnakov Institute of General and Inorganic Chemistry Academy of Science, 117973, Moscow, USSR

    Inessa A. Zakharova

Authors
  1. Mariano Casu
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  2. Adolfo Lai
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  3. Gioanna Gelli
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  4. Gustavo Ponticelli
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  5. Inessa A. Zakharova
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Casu, M., Lai, A., Gelli, G. et al. An n.m.r. study on displacements from platinum(II) complexes by dimethylsulphoxide. Transition Met Chem 12, 341–344 (1987). https://doi.org/10.1007/BF01024029

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  • DOI: https://doi.org/10.1007/BF01024029

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