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Terpenes in organic synthesis. 7. Synthesis of (S)-(+)-3-methylheneicosan-2-one from (s)-(+)-3,7-dimethylocta-1,6-diene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

From (S)-(+)-3,7-dimethylocta-1,6-diene there has been synthesized (S)-(+)-3-methyl-heneicosan-2-one, a biologically active analog of the sex pheromone of the German cockroachBlatella germanica.

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Literature cited

  1. Nguen Kong Khao, M. V. Mavrov, and É. P. Serebryakov, Izv. Akad. Nauk SSSR, Ser. Khim., 906 (1987).

  2. R. Rossi, A. Carpita, and M. Marasco, Chim. Ind. (Milano),63, 503 (1981).

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  3. Nguen Kong Khao, M. V. Mavrov, and E. P. Serebryakov, Zh. Org. Khim.,23, 1649 (1987).

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For previous communication, see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 693–695, March, 1988.

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Khao, N.K., Mavrov, M.V. & Serebryakov, É.P. Terpenes in organic synthesis. 7. Synthesis of (S)-(+)-3-methylheneicosan-2-one from (s)-(+)-3,7-dimethylocta-1,6-diene. Russ Chem Bull 37, 592–594 (1988). https://doi.org/10.1007/BF00965387

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  • DOI: https://doi.org/10.1007/BF00965387

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