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Reaction sequence arylsulfenyl chloride + alkoxyalkene-I + alkoxyalkene-II + allylmagnesium or boron derivatives as a new method for the controlled synthesis of polyfunctional derivatives

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

A new method is proposed for the controlled synthesis of polyfunctional compounds with formation of two new carbon-carbon bonds; the method is based on the following reaction sequence, which can be carried out in a single flask: addition of ArSCl to vinyl ether I, reaction of the resultant adduct with vinyl ether II in the presence of Lewis acid to form a cationic complex, and treatment of the latter with allyl derivatives of boron or magnesium.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1100–1107, May, 1991.

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Smolyakova, I.P., Smit, V.A., Bubnov, Y.N. et al. Reaction sequence arylsulfenyl chloride + alkoxyalkene-I + alkoxyalkene-II + allylmagnesium or boron derivatives as a new method for the controlled synthesis of polyfunctional derivatives. Russ Chem Bull 40, 981–987 (1991). https://doi.org/10.1007/BF00961360

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  • DOI: https://doi.org/10.1007/BF00961360

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