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Effect of base on the state of palladium in the synthesis of styrene in the heck reaction

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

An extremely important role is shown for the tertiary amine in the reduction of Pd(II) formed as result of the reductive transformations of the aryl halide in the Heck reaction. The dependence of the rate on the nature of the base is explained.

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Literature cited

  1. I. I. Moiseev, π-Complexes in the Liquid-Phase Oxidation of Olefins [in Russian], Khimiya, Moscow (1970), p. 45.

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  2. R. F. Heck, J. Am. Chem. Soc.,12, 213 (1982).

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  3. West German Patent No. 1,904,235 (1974).

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    A. F. Shmidt, L. V. Mametova, T. V. Dmitrieva, E. Yu. Shmidt & V. S. Tkach

Authors
  1. A. F. Shmidt
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  2. L. V. Mametova
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  3. T. V. Dmitrieva
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  4. E. Yu. Shmidt
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  5. V. S. Tkach
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, p. 208, January, 1991.

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Shmidt, A.F., Mametova, L.V., Dmitrieva, T.V. et al. Effect of base on the state of palladium in the synthesis of styrene in the heck reaction. Russ Chem Bull 40, 190 (1991). https://doi.org/10.1007/BF00959660

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  • DOI: https://doi.org/10.1007/BF00959660

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