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Stable bis(1-bromo-2,2,2-trihaloalkoxy)phosphoranes from tetrafluoropropyl difluorophosphite

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

It was found that dibromo-2,2,3,3-tetrafluoropropoxydifluorophosphorane, obtained from 2,2,3,3-tetrafluoropropyl difluorophosphite and bromine, adds two moles of chloral or bromal with the formation of stable 2,2,3,3-tetrafluoropropoxybis(1-bromo-2,2,2-trihaloethoxy)difluorophosphoranes, the structure of which was confirmed by NMR data.

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Literature cited

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Authors and Affiliations

  1. V. I. Ul'yanov-Lenin Kazan State University, USSR

    V. F. Mironov, E. N. Ofitserov, I. V. Konovalova, P. P. Chernov & A. N. Pudovik

Authors
  1. V. F. Mironov
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  2. E. N. Ofitserov
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  3. I. V. Konovalova
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  4. P. P. Chernov
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  5. A. N. Pudovik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2118–2120, September, 1990.

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Mironov, V.F., Ofitserov, E.N., Konovalova, I.V. et al. Stable bis(1-bromo-2,2,2-trihaloalkoxy)phosphoranes from tetrafluoropropyl difluorophosphite. Russ Chem Bull 39, 1929–1931 (1990). https://doi.org/10.1007/BF00958264

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  • DOI: https://doi.org/10.1007/BF00958264

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