Abstract
The electronic structure of allenyl vinyl ethers (I) has been studied with the aid of photoelectron and UV spectroscopy, as well as MNDO and CNDO/S quantumchemical calculations. Divinyl ether has been selected as a model system for these molecules. The photoelectron spectra of I are similar to the spectrum of divinyl ether, with the exception of the band at 10.2–10.6 eV. The long-wavelength band in the UV spectra of I has been assigned to a transition localized in the allene group. The short-wavelength band of I corresponds to the π → π* transition observed in divinyl ether.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2011–2014, September, 1989.
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Eroshchenko, S.V., Sinegovskaya, L.M., Tarasova, O.A. et al. Photoelectron and ultraviolet absorption spectra of allenyl vinyl ethers. Russ Chem Bull 38, 1848–1851 (1989). https://doi.org/10.1007/BF00957775
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DOI: https://doi.org/10.1007/BF00957775