Conclusions
The isomeric 3-methyl-4-norcaranones have predominantly the conformation with a syn orientation of the three-membered ring and carbonyl group. The conformations of the cis-and trans-3-methyl-2-norcaranones are determined by the equatorial position of the methyl group.
Literature cited
A. N. Vereshchagin, S. G. Vul'fson, and B. A. Arbuzov, Izv. Akad. Nauk SSSR, Ser. Khim., 1026 (1974).
H. Kuczynsky, K. Piatkovski, Ch. A. Hendu, and A. Kubik, Roczniki Chem.,42, 69 (1968).
A. P. Anastas'eva, Dissertation [in Russian], Kazan (1970).
V. A. Naumov, Dissertation [in Russian], Kazan (1972).
B. A. Arbuzov, S. G. Vul'fson, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 306 (1971).
S. P. Acharya and H. C. Brown, J. Am. Chem. Soc,89, 1925 (1967).
É. Kh. Kazakova, L. N. Surkova, and Sh. S. Bikeev, Izv. Akad. Nauk SSSR, Ser. Khim., 875 (1980).
E. Toromanoff, Bull. Soc. Chim. France, 2457 (1968).
W. K. Grant and J. C. Speakman, Acta Cryst.,15, 292 (1962).
B. A. Arbuzov, L. A. Grozina, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 2370 (1969).
A. N. Vereshchagin, Polarizability of Molecules [in Russian], Nauka, Moscow (1980), p. 94.
B. Rickborn and S. Lwo, J. Org. Chem.,30., 2212 (1965).
E. Iliel, N. Allinger, S. Enjial, and G. Morrison, Conformation Analysis [Russian translation], Mir, Moscow (1969), p. 529.
F. Rocouet and A. Sevin, Bull. Soc. Chim. France, 895 (1974).
É. Kh. Kazakova, Z. G. Isaeva, and Sh. S. Bikeev, Izv. Akad. Nauk SSSR, Ser. Khim., 2330 (1979).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2156–2159, September, 1983.
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Surkova, L.N., Kovylyaeva, G.I., Kazakova, É.K. et al. Conformation of isomeric norcaranones. Russ Chem Bull 32, 1949–1951 (1983). https://doi.org/10.1007/BF00954684
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DOI: https://doi.org/10.1007/BF00954684