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Some reactions of pentafluorophenyl-substituted germanes with triphenylphosphine complexes of platinum

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A series of hydride complexes of nickel, palladium, and platinum was obtained by oxidative-addition reactions of zerovalent triphenylphosphine complexes of the metals with pentafluorophenyl-substituted germanes. The Pt-H groups in the obtained compounds were distinguished by low reactivity.

  2. 2.

    A stable complex with a Pt-Ge-Ge-Hg chain was synthesized by the reaction of HPt(PPh3)2-Ge(C6F5)2-Ge(C6F5)2H with diethylmercury.

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Literature cited

  1. E. Hengge, E. Starz, and W. Strubert, Monatsh. Chem.,99, 1787 (1968).

    Google Scholar 

  2. M. N. Bochkarev, S. P. Korneva, L. P. Maiorova, V. A. Kuznetsov, and N. S. Vyazankin, Zh, Obshch. Khim.,44, 308 (1974).

    Google Scholar 

  3. M. N. Bochkarev, G. A. Razuvaev, and N. S. Vyazankin, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 1820.

  4. M. N. Bochkarev, G. A. Razuvaev, L. P. Maiorova, N. P. Makarenko, V. I. Sokolov, V. V. Bashilov, and O. A. Reutov, J. Organomet. Chem.,131, 399 (1977).

    Google Scholar 

  5. M. N. Bochkarev, L. P. Maiorova, and N. S. Vyazankin, J. Organomet. Chem.,55, 89 (1973).

    Google Scholar 

  6. R. J. Gross and F. Glockling, J. Chem. Soc.,1965, 5422.

  7. F. Glockling and K. A. Hooton, J. Chem. Soc., A1967, 1066.

  8. M. N. Bochkarev, L. P. Maiorova, S. P. Korneva, L. N. Bochkarev, and N. S. Vyazankin, J. Organomet. Chem.,73, 229 (1974).

    Google Scholar 

  9. M. N. Bochkarev, L. P. Maiorova, N. S. Vyazankin, and G. A. Razuvaev, J. Organomet. Chem.,82, 65 (1974).

    Google Scholar 

  10. L. Malatesta and C. Cariello, J. Chem. Soc.,1958, 2323.

  11. J. Takahashi, T. Ito, S. Sakai, and Y. Ishii, J. Chem. Soc., D1970, 1065.

  12. M. Hidai, T. Kashiwagi, T. Ikeuchi, and Y. Uchida, J. Organomet. Chem.,30, 279 (1971).

    Google Scholar 

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1854–1858, August, 1979.

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Bochkarev, M.N., Maiorova, L.P., Skobeleva, S.E. et al. Some reactions of pentafluorophenyl-substituted germanes with triphenylphosphine complexes of platinum. Russ Chem Bull 28, 1717–1722 (1979). https://doi.org/10.1007/BF00951001

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  • DOI: https://doi.org/10.1007/BF00951001

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