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Effect of electron-donor complexing additives on the activity of nickel acetylacetonate in the catalyzed oxidation of ethylbenzene

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Electron-donor complexing additives (D=HMPA, MP, DMFA) increase the initial rate of the Ni(acac)2-catalyzed ethylbenzene oxidation, and shift the selectivity toward the formation ofα-phenylethyl hydroperoxide.

  2. 2.

    In systems containing Ni(acac)2 and an electron-donor additive, the relation between the initial oxidation rate and the additive concentration is of an extremal type.

  3. 3.

    Rates have been measured for chain initiation and branching in the oxidation of ethylbenzene in systems containing Ni(acac)2 and electron-donor additives.

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Literature cited

  1. L. A. Mosolova, L. I. Matienko, and Z. K. Maizus, Izv. Akad. Nauk SSSR, Ser. Khim., 1760 (1978).

  2. L. A. Mosolova, L. I. Matienko, and Z. K. Maizus, Izv. Akad. Nauk SSSR, Ser. Khim., 278 (1980).

  3. N. N. Vorozhtsov, Principles of the Synthesis of Intermediate Products and Dye Stuffs [in Russian], Goskhimizdat, Moscow (1955).

    Google Scholar 

  4. V. Gutman, Coord. Chem. Rev.,18, 225 (1976).

    Google Scholar 

  5. V. Gutman, Coord. Chem. Rev.,12, 263 (1974).

    Google Scholar 

  6. D. Goeffrey, F. El.-S. Mohamed, and W. R. Martin, J. Chem. Soc. Chem. Commun., 1045 (1978).

  7. L. I. Matienko and Z. K. Maizus, Kinet. Katal.,15, 317 (1974).

    Google Scholar 

  8. Y. Ohkatzu and T. Osa, Bull. Chem. Soc. Jpn.,50, 2945 (1977).

    Google Scholar 

  9. R. Muller and D. Wohrle, Makromol. Chem.,179, 2161 (1978).

    Google Scholar 

  10. M. J. Carter, D. P. Rillema, and F. Basolo, J. Am. Chem. Soc.,96, 392 (1974).

    Google Scholar 

  11. Von G. Henrici-Olive and S. Olive, Angew. Chem.,86, 1 (1974).

    Google Scholar 

  12. G. M. Larin, V. V. Minin, É. G. Éger, and P. Renner, Zh. Neorg. Khim.,25, 183 (1980).

    Google Scholar 

  13. R. P. Eckberg, J. H. Nelson, J. W. Kenney, R. N. Howells, and R. A. Henry, Inorg. Chem.,16, 3128 (1977).

    Google Scholar 

  14. P. K. Chattopadhyay and B. Kratochvil, Can. J. Chem.,55, 3449 (1977).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    L. A. Mosolova, L. I. Matienko & Z. K. Maizus

Authors
  1. L. A. Mosolova
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  2. L. I. Matienko
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  3. Z. K. Maizus
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 731–735, April, 1981.

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Mosolova, L.A., Matienko, L.I. & Maizus, Z.K. Effect of electron-donor complexing additives on the activity of nickel acetylacetonate in the catalyzed oxidation of ethylbenzene. Russ Chem Bull 30, 520–523 (1981). https://doi.org/10.1007/BF00949702

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  • DOI: https://doi.org/10.1007/BF00949702

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