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C-alkylation of N-alkylanilines by polyfluoroketones

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Conditions were found for the mild C-alkylation of secondary and tertiary aromatic amines by hexafluoroacetone and methyl trifluoropyruvate. The regiospecific formation of the products of C(4)-alkylation was demonstrated.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. E. Zelenin, N. D. Chkanikov, M. V. Galakhov, A. F. Kolomiets & A. V. Fokin

Authors
  1. A. E. Zelenin
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  2. N. D. Chkanikov
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  3. M. V. Galakhov
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  4. A. F. Kolomiets
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  5. A. V. Fokin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 931–934, April, 1985.

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Zelenin, A.E., Chkanikov, N.D., Galakhov, M.V. et al. C-alkylation of N-alkylanilines by polyfluoroketones. Russ Chem Bull 34, 850–853 (1985). https://doi.org/10.1007/BF00948075

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  • DOI: https://doi.org/10.1007/BF00948075

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