Skip to main content
Log in

Kinetics of the reactions of substituted benzoquinones with alkyl radicals

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Study has been made of the kinetics of the reactions of sec-decyl radicals with 2,6-di-tert-butyl-, and 2,6-diphenyl-p-benzoquinone, and 2,4- and 2,5-di-tert-butyl-o-benzoquinones at 50°C. Rate constants and inhibition coefficients have been determined for these reactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. C. D. Cook, R. Woodworth, and P. Finou, J. Am. Chem. Soc.,78, 4159 (1956).

    Google Scholar 

  2. V. A. Roginskii, L. G. Plekhanova, V. Z. Dubinskii, G. A. Nikiforov, V. B. Miller, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 1327.

  3. C. R. H. J. de Jonge, H. J. Hageman, W. G. B. Huysmans, and W. J. Mijs, J. Chem. Soc. Perkin Trans. 2,1973, 1276.

    Google Scholar 

  4. E. T. Denisov, Klnet. Katal.,15, 1422 (1974).

    Google Scholar 

  5. J. L. Kice, J. Am. Chem. Soc.,76, 6274 (1954); J. Polym. Sci.,19, 123 (1956).

    Google Scholar 

  6. A. Rembaum and M. Szwarc, J. Am. Chem. Soc.,77, 4468 (1955).

    Google Scholar 

  7. J. W. Breitenbach, Z. Elektrochem.,60, 286 (1956).

    Google Scholar 

  8. Z. S. Kartasheva, A. B. Gagarina, and N. M. Émanuél, Dokl. Akad. Nauk SSSR,229, 663 (1976).

    Google Scholar 

  9. E. T. Denisov, Izv. Akad. Nauk SSSR, Ser. Khim.,1963, 2037.

  10. A. F. Bickel and E. C. Kooyman, J. Chem. Soc.,1953, 3211.

  11. V. A. Roginskii and V. A. Belyakov, Dokl. Akad. Nauk SSSR,237, 1404 (1977).

    Google Scholar 

  12. V. Z. Dubinskii, Dissertation, Moscow, (1977).

  13. E. T. Denisov, Rate Constants for Homolytic Liquid-phase Reactions [in Russian], Nauka (1971).

  14. R. D. Parnell and K. E. Russell, J. Polym. Sci., A1,12, 347 (1974).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2487–2491, November, 1978.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shlyapnikova, I.A., Roginskii, V.A. & Miller, V.B. Kinetics of the reactions of substituted benzoquinones with alkyl radicals. Russ Chem Bull 27, 2215–2219 (1978). https://doi.org/10.1007/BF00946664

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00946664

Keywords

Navigation