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Determination of the conformations of conjugated systems of the diphenyl type by a refractometric method

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A refractometric method was developed for the determination of the conformations of conjugated systems of the diphenyl type.

  2. 2.

    The possibility of the use of correlation equations for the calculation of the exaltation and refraction of coplanar diphenyls in the liquid state was demonstrated.

  3. 3.

    The angle of rotation between the benzene rings in certain alkyl- and halodiphenyls was estimated quantitatively.

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Literature cited

  1. A. I. Kitaigorodskii, Organic Crystal Chemistry [in Russian], Izd-vo Akad. Nauk SSSR (1955), p. 383.

  2. H. Suzuki, Electronic Absorption Spectra and Geometry of Organic Molecules, Academic Press, New York-London (1967), pp. 261–292.

    Google Scholar 

  3. O. Bastiansen, Acta Chem. Scand.,3, 408 (1949);4, 926 (1950);8, 1593 (1954).

    Google Scholar 

  4. E. A. Braude and W. F. Forbes, J. Chem. Soc., 3776 (1955).

  5. Steric Effects in Conjugated System, Ed. G. W. Gray, Butterworth, London (1958).

    Google Scholar 

  6. A. C. Littlejohn and J. W. Smith, J. Chem. Soc., 2456 (1953); 2552(1954).

  7. R. J. W. Le Fèvre, A. Sundaram, and K. M. S. Sundaram, J. Chem. Soc., 3180 (1963).

  8. A. Unanue and P. Bothorel, Bull. Soc. Chim. France, 1640 (1966).

  9. P. Bothorel and A. Unanue, Bull. Soc. Chim. France, 754 (1968).

  10. V. M. Wepster, Progress in Stereochemistry, Ed. W. Klyne, Vol. 2; Academic Press, New York -London (1958), p. 99.

  11. L. Ingrahm, Steric Effects in Organic Chemistry [Russian translation], IL (1960), p. 486.

  12. E.A. Braude and F. Sondheimer, J. Chem. Soc., 3754 (1955); B. M. Wepster, Recueil Trav. Chim.,76, 335 (1957); J. Burgers, M. A. Hoefnagel, P. E. Verkade, H. Visser, and B. M. Wepster, Ibid.,77, 491 (1958).

  13. R. J. W. Le Fèvre, L. Radom, and G. L. D. Richie, J. Chem. Soc., B, 775 (1968).

  14. B. A. Zaitsev, Reakts. Sposobnost' Organ. Soed.,7, 1016 (1970); K. S. Dhami and J. B. Stothers, Tetrahedron Letters, 631 (1964).

  15. B. V. Ioffe, Refractometric Methods of Chemistry [in Russian], Khimizdat, Leningrad (1960), pp. 158–160.

    Google Scholar 

  16. B. A. Zaitsev, Reakts. Sposobnost' Organ. Soed.,4, 337, 357, 726, 740 (1967); Vysokomolekul. Soed.,A9, 2343 (1967).

    Google Scholar 

  17. B. A. Zaitsev, Izv. Akad. Nauk SSSR, Ser. Khim., 2400 (1972); 1968 (1973); 780 (1974).

  18. B. A. Zaitsev, Reakts. Sposobnost' Organ. Soed.,6, 398, 414, 1023, 1034, 1045 (1969).

    Google Scholar 

  19. B.Beilstein, Handbuch der Organ. Chem., III Ergänzungswerk, Vol. 5, Part 3, Springer-Verlag (1964), pp. 1353, 1373, 1728.

  20. B. A. Zaitsev, Reakts. Sposobnost' Organ. Soed.,9, 65 (1972).

    Google Scholar 

  21. J. H. Weisburger, K. Weisburger, and F. E. Ray, J. Amer. Chem. Soc.72, 4250 (1950).

    Google Scholar 

  22. D. M. Burns and J. Iball, Proc. Roy. Soc., A,227, 200 (1955).

    Google Scholar 

  23. R. R. Dreisbach, Physical Properties of Chemical Compounds, Amer. Chem. Soc., Washington (1955, 1959, 1961).

  24. A. I. Vogel, J. Chem. Soc., 1833 (1948).

  25. J. Y. H. Chay, C. G. Le Févre, R. J. W. Le Févre, J. Chem. Soc., 2666 (1959).

  26. F. Krollpfeiffer, Liebigs Ann. Chem.,430, 161 (1923).

    Google Scholar 

  27. H. G. Davis and S. Gottlieb, Fuel,42, 37 (1963).

    Google Scholar 

  28. O. E. Hyghes, C. G. Le Fevre, and R. J. W. Le Fèvre, J. Chem. Soc., 203 (1937).

  29. J. Schuyer, L. B. Blom, and D. W. Krevelen, Trans. Faraday Soc.,49, 1391 (1953).

    Google Scholar 

  30. G. Egloff, Physical Constants of Hydrocarbons,3, 324 (1946).

    Google Scholar 

  31. Dictionary of Organic Compounds, Vol. 2, London (1965), p. 1153.

  32. I. A. Goodman and P. H. Wise, J. Amer. Chem. Soc.,72, 3076 (1950).

    Google Scholar 

  33. E. P. Kaplan, Z. I. Kazakova, and A. D. Petrov, Izv. Akad. Nauk SSSR, Ser. Khim., 1440 (1966).

  34. S. W. Ferris, Handbook of Hydrocarbons, Academic Press, N. Y. (1955).

    Google Scholar 

  35. S. Samoilov and M. Dyatkina, Zh. Fiz. Khimii,22, 1294 (1948); F. J. Adrian, J. Chem. Phys.,28, 608 (1958).

    Google Scholar 

  36. I. L. Kotlyarevskii, M. S. Shvartsberg, and L. B. Fisher, Reactions of Acetylene Compounds [in Russian], “Nauka,” Novosibirsk (1967), p. 272.

    Google Scholar 

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Authors and Affiliations

  1. Institute of High-Molecular-Weight Compounds, Academy of Sciences of the USSR, Leningrad

    B. A. Zaitsev & G. I. Khramova

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  1. B. A. Zaitsev
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  2. G. I. Khramova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2722–2730, December, 1974.

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Zaitsev, B.A., Khramova, G.I. Determination of the conformations of conjugated systems of the diphenyl type by a refractometric method. Russ Chem Bull 23, 2629–2635 (1974). https://doi.org/10.1007/BF00923694

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  • DOI: https://doi.org/10.1007/BF00923694

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