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Dehydrochlorination of polychloroalkanes that contain the CH3CCl2CH2 CHCl group

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The catalytic dehydrochlorination of compounds of general formula CH3CCl2CH2CHClX (X = H, Cl, CH3) under the influence of Friedel-Crafts catalysts is accomplished via the chlorine of the dichloromethylene group toward both the methyl and the methylene groups.

  2. 2.

    The alkaline dehydrochlorination of the same compounds proceeds with the involvement of the hydrogen of the methylene group and the chlorine of both chlorine-containing groups.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    T. T. Vasil'eva, L. N. Sokolova, V. I. Dostovalova & R. Kh. Freidlina

Authors
  1. T. T. Vasil'eva
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  2. L. N. Sokolova
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  3. V. I. Dostovalova
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  4. R. Kh. Freidlina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 622–627, March, 1974.

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Vasil'eva, T.T., Sokolova, L.N., Dostovalova, V.I. et al. Dehydrochlorination of polychloroalkanes that contain the CH3CCl2CH2 CHCl group. Russ Chem Bull 23, 586–590 (1974). https://doi.org/10.1007/BF00921150

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  • DOI: https://doi.org/10.1007/BF00921150

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