Conclusions
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1.
The basicity of amines of the type\(- > E1 - \mathop C\limits_|^| - N<\) varies in the following order: Si> Sn>Ge> C.
-
2.
The data obtained previously on the intramolecular coordination bond in aminomethylstannanes were refuted.
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For Communication 6, see [1].
The article is published on the basis of a resolution of the Conference of Editors-in-Chief of the Journals of the Academy of Sciences of the USSR, of July 12, 1962, as the dissertation work of A. K. Prokof'ev.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 794–801, April, 1967.
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Prokof'ev, A.K., Nechiporenko, V.P. & Kostyanovskii, R.G. Geminal systems. Russ Chem Bull 16, 765–771 (1967). https://doi.org/10.1007/BF00915652
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DOI: https://doi.org/10.1007/BF00915652