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Alkylation of phenols with compounds with mixed functions

Communication 4. Alkenylation of m- and p-cresols with 4-penten-l-OL

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    An investigation was made of the alkenylation of m- and p-cresols with 4-penten-1-ol in presence of phosphoric acid.

  2. 2.

    As a result of the alkenylation the corresponding (methylbutenyl) cresols and their cyclization products (chromanes) were obtained.

  3. 3.

    The alkenylation of cresols with 4-penten-1-ol proceeds by a mechanism that differs from that of alkenylation with allyl alcohol. 1,4-Pentadiene forms an intermediate product in the reaction.

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Literature cited

  1. N. I. Shuikin, E. A. Viktorova and I. E. Pokrovskaya, Izv. AN SSSR. Otd. khim. n.1961, 1094.

  2. N. I. Shuikin, E. A. Viktorova, I. E. Pokrovskaya and T. G. Malysheva, Izv. AN SSSR. Otd. khim. n.1961, 1660.

  3. N. I. Shuikin, E. A. Viktorova, I. E. Pokrovskaya and T. G. Malysheva, Izv. AN SSSR. Otd. khim. n.1961 1847.

  4. E. A. Viktorova, N. I. Shuikin and G. V. Popova, Vestnik MGU, No. 6, 62 (1960).

    Google Scholar 

  5. E. A. Viktorova, N. I. Shuikin and B. G. Bubnova, Izv. AN SSSR. Otd. khim. n.1961, 000.

  6. W. Kirner, J. Amer. Chem. Soc.52, 3251 (1930).

    Google Scholar 

  7. S. Solaway, A. Santoro, Analyt. Chem27, 798 (1955).

    Google Scholar 

  8. T. Kenzo, J. Chem. Soc. Japan,80, No. 6, 687 (1959).

    Google Scholar 

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    N. I. Shuikin, E. A. Viktorova, I. E. Pokrovskaya & T. G. Malysheva

Authors
  1. N. I. Shuikin
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  2. E. A. Viktorova
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  3. I. E. Pokrovskaya
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  4. T. G. Malysheva
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Shuikin, N.I., Viktorova, E.A., Pokrovskaya, I.E. et al. Alkylation of phenols with compounds with mixed functions. Russ Chem Bull 10, 1725–1728 (1961). https://doi.org/10.1007/BF00911449

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  • DOI: https://doi.org/10.1007/BF00911449

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