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Study of the structure and reactivity of nitrogen-containing derivatives of carbonyl compounds

Communication 26. Polarographic reduction of arylhydrazones of methylglyoxal and the ethyl ester of diketobutyric acid

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The arylhydrazones of methylglyoxal and diketobutyric acid are reduced in buffer solutions in two steps: in the first step reduction takes place to the aromatic amine and aminoketone, with an expenditure of four electrons. In the second step there is a two-electron reduction of the aminoketone.

  2. 2.

    In unbuffered aqueous and alcohol solutions, the electrode processes include only the first step.

  3. 3.

    An important role of adsorption of the molecules of the substances studied in the processes occurring on the electrode was detected.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    Yu. P. Kitaev, G. K. Budnikov & L. I. Maslova

Authors
  1. Yu. P. Kitaev
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  2. G. K. Budnikov
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  3. L. I. Maslova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1911–1917, September, 1967.

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Kitaev, Y.P., Budnikov, G.K. & Maslova, L.I. Study of the structure and reactivity of nitrogen-containing derivatives of carbonyl compounds. Russ Chem Bull 16, 1835–1840 (1967). https://doi.org/10.1007/BF00909567

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  • DOI: https://doi.org/10.1007/BF00909567

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