Summary
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1.
The rearrangements of quinobromides prepared from 2,4,6-trialkylphenols (2,4,6-trialkyl-4-bromo-2,5cyclohexadien-1-ones) into 3,5-dialkyl-4-hydroxybenzyl bromides were carried out.
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With the reaction with piperidine as example, it was shown to be possible to use 3,5-dialkyl-4-hydroxybenzyl bromides as alkylating agents.
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The authors thank N. M. Émanuél' for constant interest in the work.
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Volod'kin, A.A., Ershov, V.V. Sterically hindered phenols. Russ Chem Bull 11, 1213–1215 (1962). https://doi.org/10.1007/BF00908403
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DOI: https://doi.org/10.1007/BF00908403