Conclusions
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1.
Bis(dimethylglyoximato)triphenylphosphinerhodiumhydride is a catalyst for selective reduction of butadiene with molecular hydrogen or NaBH4.
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2.
Bis(dimethylglyoximato)triphenylphosphine-2-butenerhodium, the product of butadiene addition to the rhodium hydride complex, was isolated. It was proposed that this compound is the intermediate in the reaction of catalytic reduction of butadiene.
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Literature cited
V. B. Panov, M. L. Khidekel', and S. A. Shchepinov, Izv. Akad. Nauk SSSR, Ser. Khim., 2397 (1968).
S. A. Shchepinov, E. N. Sal'nikova, and M. L. Khidekel', Izv. Akad. Nauk SSSR, Ser. Khim., 2129 (1967).
Taiichi Miruta and Ta Kao Kwan, J. Chem. Soc. Japan,88, No. 4, 471 (1967).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 141–142, January, 1969.
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Rogachev, B.G., Khidekel', M.L. Selective reduction of butadiene in the presence of the bisdimethylglyoximate complex of rhodium. Russ Chem Bull 18, 127–128 (1969). https://doi.org/10.1007/BF00907608
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DOI: https://doi.org/10.1007/BF00907608