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Mechanism of the 1,3-dipolar cycloaddition of nitrone ethers

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The velocity constants of the cycloaddition of 3-nitroisoxazoline N-oxide to styrene in various solvents have been determined.

  2. 2.

    The velocity constants of the cycloaddition of 3-nitroisoxazoline N-oxide to hex-1-ene, methyl acrylate, and vinyl ethyl ether in dioxane have been determined.

  3. 3.

    The cycloaddition of 3-nitroisoxazoline N-oxide to olefins is a multicenter synchronous process.

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Literature cited

  1. V. A. Tartakovskii, I. E. Chlenov, S. S. Smagin, and S. S. Novikov, Izv. AN SSSR, Ser. khim.,1964, 583.

  2. R. Huisgen, Angew. Chem.,75, 742 (1963).

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  3. V. A. Tartakovskii, A. A. Onishchenko, V. A. Smirnyagin, and S. S. Novikov, Zh. organ, khimii,2, 2095 (1966).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    V. A. Tartakovskii, A. A. Onishchenko & S. S. Novikov

Authors
  1. V. A. Tartakovskii
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  2. A. A. Onishchenko
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  3. S. S. Novikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 177–179, January, 1967.

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Tartakovskii, V.A., Onishchenko, A.A. & Novikov, S.S. Mechanism of the 1,3-dipolar cycloaddition of nitrone ethers. Russ Chem Bull 16, 166–168 (1967). https://doi.org/10.1007/BF00907123

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  • DOI: https://doi.org/10.1007/BF00907123

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