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Intramolecular hydride transfer in the ionic hydrogenation of isopropylcyclopropane

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

It was shown that in the ionic hydrogenation of isopropylcyclopropane simultaneously with cleavage of the ring there is an intramolecular hydride transition with the formation of a tertiary carbonium ion, which splits a hydride ion from silane.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    D. N. Kursanov, G. A. Khotimskaya, É. I. Fedin, M. Yu. Lukina & Z. N. Parnes

  2. Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR

    D. N. Kursanov, G. A. Khotimskaya, É. I. Fedin, M. Yu. Lukina & Z. N. Parnes

Authors
  1. D. N. Kursanov
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  2. G. A. Khotimskaya
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  3. É. I. Fedin
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  4. M. Yu. Lukina
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  5. Z. N. Parnes
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 746–748, April, 1969.

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Kursanov, D.N., Khotimskaya, G.A., Fedin, É.I. et al. Intramolecular hydride transfer in the ionic hydrogenation of isopropylcyclopropane. Russ Chem Bull 18, 679–681 (1969). https://doi.org/10.1007/BF00907019

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  • DOI: https://doi.org/10.1007/BF00907019

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