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The effect of spatial factors on the reaction of arylmercuric hydroxides with N-acids

Communication 2. Phenylmercuric derivatives of sulfamides, cyclic amides, and some heterocyclics

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of phenylmercuric hydroxide with a series of cyclic-N-acids and sulfamides was investigated.

  2. 2.

    The compounds mentioned above, in contrast to the noncyclic analogs studied earlier with a conformation stabilized by conjugation, form C6H5Hg derivatives.

  3. 3.

    Steric hindrances, created by groups whose conformation is not immobilized by resonance, do not hinder the formation of phenylmercuric derivatives of the N-acids.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1741–1747, August, 1967.

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Kravtsov, D.N., Nesmeyanov, A.N. The effect of spatial factors on the reaction of arylmercuric hydroxides with N-acids. Russ Chem Bull 16, 1674–1678 (1967). https://doi.org/10.1007/BF00906811

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  • DOI: https://doi.org/10.1007/BF00906811

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