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Fluorine-containing β-sultones

Communication 31. Reaction of β-sultones with sulfuric acid

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of tetrafluoroethane-β-sultone with H2SO4 was investigated. One of the reaction products was the unstable trifluorovinylsulfuric acid, which decomposes to form difluoroketene.

  2. 2.

    The stability of the alkylpolyfluoroalkenyl sulfates was investigated, and their ability to change into alkyl fluorosulfates was demonstrated.

  3. 3.

    Thermal decomposition of hexafluoropropane-2-β-sultone in the presence of H2SO4 takes place with the formation ofα-hydrotetrafluoropropionyl fluoride.

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Literature cited

  1. G. A. Sokol'skii, M. A. Belaventsev, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 2020 (1967).

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  7. L. I. Ragulin, M. A. Belaventsev, G. A. Sokol'skii, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 2304 (1968).

  8. I. L. Knunyants, M. A. Belaventsev, P. P. Ropalo, and G. A. Sokol'skii, Izv. Akad. Nauk SSSR, Ser. Khim., 1027 (1966).

  9. I. L. Knunyants, G. A. Sokol'skii, and M. A. Belaventsev, Izv. Akad. Nauk SSSR, Ser. Khim., 1017 (1966).

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Authors
  1. L. I. Ragulin
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  2. M. A. Belaventsev
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  3. G. A. Sokol'skii
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  4. I. L. Knunyants
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Additional information

Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 10, pp. 2220–2224, October, 1969.

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Ragulin, L.I., Belaventsev, M.A., Sokol'skii, G.A. et al. Fluorine-containing β-sultones. Russ Chem Bull 18, 2070–2073 (1969). https://doi.org/10.1007/BF00906621

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  • DOI: https://doi.org/10.1007/BF00906621

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