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Influence of steric factors on the electrochemical reduction of bromo-derivatives of 7-oxabicyclo-[2,2,1]heptane

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The influence of the steric position of the bromine atom on the parameters of the polarographic reduction of certain bromo-derivatives of 7-oxabicyclo[2,2,l]heptane was considered.

  2. 2.

    Bromine in the exo-position is reduced more readily than bromine in the endo-position. The reduction of vicinal dibromides, bromohydrins, and acetylbromohydrins apparently occurs according to a 1,2-elimination mechanism.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 254–258, February, 1969.

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Butin, K.P., Belokoneva, N.A., Eldikov, V.N. et al. Influence of steric factors on the electrochemical reduction of bromo-derivatives of 7-oxabicyclo-[2,2,1]heptane. Russ Chem Bull 18, 214–217 (1969). https://doi.org/10.1007/BF00905521

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  • DOI: https://doi.org/10.1007/BF00905521

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