Conclusions
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1.
The influence of the steric position of the bromine atom on the parameters of the polarographic reduction of certain bromo-derivatives of 7-oxabicyclo[2,2,l]heptane was considered.
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2.
Bromine in the exo-position is reduced more readily than bromine in the endo-position. The reduction of vicinal dibromides, bromohydrins, and acetylbromohydrins apparently occurs according to a 1,2-elimination mechanism.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 254–258, February, 1969.
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Butin, K.P., Belokoneva, N.A., Eldikov, V.N. et al. Influence of steric factors on the electrochemical reduction of bromo-derivatives of 7-oxabicyclo-[2,2,1]heptane. Russ Chem Bull 18, 214–217 (1969). https://doi.org/10.1007/BF00905521
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DOI: https://doi.org/10.1007/BF00905521