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Oligomerization of ethylene under the influence of bis-(π-allylnickel bromide) in conjunction with lewis acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The percentage of 1-butene in the dimer is ∼50% in the products of oligomerization of ethylene under the influence ofπ-allylnickel bromide in conjunction with various Lewis acids (L) at an L/Ni molar ratio of 1 to 2.

  2. 2.

    The composition of the products of the oligomerization of ethylene attests to the important role played by complex nickel hydrides in this reaction.

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Literature cited

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, USSR

    S. G. Abasova, A. I. Leshcheva, E. A. Mushina, V. Sh. Fel'dblyum & B. A. Krentsel'

  2. Institute of Monomers for Synthetic Rubber, USSR

    S. G. Abasova, A. I. Leshcheva, E. A. Mushina, V. Sh. Fel'dblyum & B. A. Krentsel'

Authors
  1. S. G. Abasova
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  2. A. I. Leshcheva
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  3. E. A. Mushina
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  4. V. Sh. Fel'dblyum
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  5. B. A. Krentsel'
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 644–646, March, 1972.

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Abasova, S.G., Leshcheva, A.I., Mushina, E.A. et al. Oligomerization of ethylene under the influence of bis-(π-allylnickel bromide) in conjunction with lewis acids. Russ Chem Bull 21, 608–609 (1972). https://doi.org/10.1007/BF00863224

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  • DOI: https://doi.org/10.1007/BF00863224

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