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Vibrational spectra of trialkysilanes of the series (CH3)n (C2 H5)3−n SiH

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The vibrational spectra of dimethylethyl-, and methyldiethyl-, and triethylsilane were investigated. The frequencies, integral and standard intensities, degrees of polarization, and half-widths of the lines were measured in the Raman spectra. The qualitative intensities and the positions of the bands for the solid, liquid, and gaseous phases were determined in the IR spectra.

  2. 2.

    The spectrographic peculiarities of the Si-H bond were studied.

  3. 3.

    The potential functions were calculated for the tetrahedral framework of the molecules.

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Literature cited

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Authors and Affiliations

  1. I. V. Grebenshchikov Institute of Silicate Chemistry, Academy of Sciences of the USSR, USSR

    I. V. Shevchenko, I. F. Kovalev, V. S. Dernova, M. G. Voronkov, Yu. I. Khudobin, N. A. Andreeva & N. P. Kharitonov

  2. Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, USSR

    I. V. Shevchenko, I. F. Kovalev, V. S. Dernova, M. G. Voronkov, Yu. I. Khudobin, N. A. Andreeva & N. P. Kharitonov

Authors
  1. I. V. Shevchenko
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  2. I. F. Kovalev
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  3. V. S. Dernova
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  4. M. G. Voronkov
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  5. Yu. I. Khudobin
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  6. N. A. Andreeva
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  7. N. P. Kharitonov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 98–106, January, 1972.

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Shevchenko, I.V., Kovalev, I.F., Dernova, V.S. et al. Vibrational spectra of trialkysilanes of the series (CH3)n (C2 H5)3−n SiH. Russ Chem Bull 21, 88–94 (1972). https://doi.org/10.1007/BF00855662

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  • DOI: https://doi.org/10.1007/BF00855662

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